据台湾媒体《东森新闻》报道，彭佳慧2006年和圈外人老公王丕仁（Steven）结婚，男方从事服装贸易，因为外型不符合条件，她曾狠心拒绝对方3次求婚，最后被老公耐心打动，结婚12年来感情甜蜜，最近却曝出她忙着经营事业，导致夫妻渐行渐远，感情因而生变，准备签字离婚。
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彭佳慧曾抱持不婚主义，在遇到老公后才打破原则，还生下1个儿子、1对双胞胎女儿，据《镜周刊》报道，她近年来事业重新攀上巅峰，以《大龄女子》夺下金曲歌后、登上小巨蛋开唱，在大陆参加《我是歌手》节目受到关注，工作邀约不断，忙着经营事业的同时，传出疏于经营夫妻感情，导致婚变。